In India 1500 V DC and 25 kV AC, 50 Hz, is used for main line trains.
The 1500 V DC overhead system (negative earth, positive catenary) is used around Mumbai. The Mumbai region is the last bastion of 1500 V DC electrified lines on Indian Railways. There are plans to change this to 25 kV AC by 2010. The 25 kV AC system with overhead lines is used throughout the rest of the country. The dual-voltage WCAM series locomotives haul intercity trains out of Mumbai DC suburban region. The new AC/DC EMU rakes used in Mumbai are also designed to operate with both DC and AC traction as the Mumbai area switches over to the 25 kV AC system.
The...
more...

Kolkata Metro uses 750 V DC traction with a third rail for delivering the electricity to the EMUs. The Kolkata trams use 550 V DC with overhead lines with underground conductors. The catenary is at a negative potential.
The Delhi Metro uses 25 kV AC overhead lines on the ground-level and elevated routes, and uses a rather unusual "rigid catenary", or overhead power rail, in the underground tunnel sections
Source: Wikipedia